Abstract

Transfer printing of high mobility inorganic nanostructures, using an elastomeric transfer stamp, is a potential route for high-performance printed electronics. Using this method to transfer nanostructures with high yield, uniformity and excellent registration over large area remain a challenge. Herein, we present the ‘direct roll transfer’ as a single-step process, i.e., without using any elastomeric stamp, to print nanoribbons (NRs) on different substrates with excellent registration (retaining spacing, orientation, etc.) and transfer yield (∼95%). The silicon NR based field-effect transistors printed using direct roll transfer consistently show high performance i.e., high on-state current (Ion) >1 mA, high mobility (μeff) >600 cm2/Vs, high on/off ratio (Ion/off) of around 106, and low hysteresis (<0.4 V). The developed versatile and transformative method can also print nanostructures based on other materials such as GaAs and thus could pave the way for direct printing of high-performance electronics on large-area flexible substrates.

Highlights

  • Advances in flexible large-area electronics (LAE) have enabled novel applications across numerous areas including wearable systems, soft robotics, bendable displays, and healthcare[1,2,3,4,5]

  • We report a simple, cost-effective, yet robust direct roll transfer printing technique and demonstrates its efficacy for high-performance electronics by developing NR-based field-effect transistors (NRFETs)

  • The printing process is displayed in the supplementary information (Supplementary video M1 and Fig. 1)

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Summary

INTRODUCTION

Advances in flexible large-area electronics (LAE) have enabled novel applications across numerous areas including wearable systems, soft robotics, bendable displays, and healthcare[1,2,3,4,5]. Transfer printing has shown good potential for realizing high-performance flexible electronic devices and circuits[7,22] with silicon and compound semiconductor material-based nanostructures (NSs) such as micro-/nano-membranes (NMs), nanoribbons (NRs), nanowires (NWs), etc. These modified transfer printing methods improve the yield and reliability of the process and further extend the transfer printing capacities to: (i) selective printing[33], (ii) arbitrary substrate integration[34], and (iii) deterministic assembly of nano to chip-scale structures[17,28,35] These modified transfer printing methods have shown good potential for flexible electronics, but they require additional excitation equipment such as laser system, and magnet actuating system, etc.

RESULTS AND DISCUSSIONS
Zumeit et al 3
Direct roll transfer printing
METHODS
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