Abstract

The photoinduced electron transfer (PIET) from the excited singlet state (<i>S</i> <sub>1</sub>) of rhodamine B to <i>i</i>-C<sub>3</sub>F<sub>7</sub>I smoothly proceeded in the presence of water. This process was supported by the fluorescence quenching of rhodamine B with addition of <i>i</i>-C<sub>3</sub>F<sub>7</sub>I in ethanol. The present method was applied to the atom-transfer radical reaction involving the cyclization step.

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