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https://doi.org/10.1002/chem.200901399
Copy DOIJournal: Chemistry – A European Journal | Publication Date: Dec 1, 2009 |
Citations: 30 |
A novel palladium catalyzed direct ortho-arylation of N-phenacylpyridinium bromide was developed. The amazing N-phenacyl group regioselectively activates the C-H bond of pyridine and automatically departs from the arylated products. A kinetic isotope effect study proved that the reaction went through a C-H-bond activation pathway and 2,6-diphenylpyridine was produced stepwise from 2-phenylpyridine.
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