Abstract
Abstract The [(R)-1-cyanoethyl-dα] group, which has a deuterium atom attached to the chiral carbon and is bonded to the cobalt atom, in a cobaloxime complex with pyridine as an axial base ligand is inverted to the opposite configuration on exposure to visible light with retention of the single crystal form. The C-D bond is not cleaved in the process of the inversion.
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