Direct numerical simulation of NH3/air combustion with H2 addition under HCCI relevant conditions

Abstract

In the present work, two-dimensional direct numerical simulations (DNS) of NH3/air turbulent combustion with H2 addition under homogeneous-charge compression ignition (HCCI) relevant conditions were performed to explore the ignition and combustion characteristics. Three hydrogen addition levels in the fuel were considered with molar fractions of 0.0 (pure ammonia), 0.1 and 0.8. The corresponding one-dimensional laminar flames were also simulated to provide reference solutions. The general combustion characteristics were first presented. It was found that turbulence and thermal stratification facilitate the ignition process. The ignition occurs earlier with increasing hydrogen addition levels and temperature fluctuations. After ignition, high heat release rate (HRR) occurs simultaneously over the entire domain with low temperature fluctuations while significant HRR occurs in narrow sheets with high temperature fluctuations. HRR is significantly enhanced in positive curvature regions of the cases with high hydrogen addition levels due to the preferential diffusion of H and other radicals. The combustion mode was examined based on the analysis of the displacement speed and species transport equation budget. The mean displacement speed is decreased with increasing temperature fluctuations and the budget analysis suggests that high temperature gradient facilitates deflagration. The reaction fronts are thinner with increasing H2 addition levels, and the combustion mode of deflagration is promoted. The effects of turbulence intensity on the flame structure and combustion mode were evaluated. The ignition occurs earlier and the area of the reaction front increases with increasing turbulence intensity. The magnitude of the temperature gradient also increases with increasing turbulence intensity, which facilitates the occurrence of deflagration. The turbulent flame structures were compared with the corresponding 0D ignition and 1D thermally stratified flame results, and it was found that the mean turbulent flame structure can be well approximated by 1D thermally stratified flames.