Abstract
We report direct measurement of collisional line-broadening coefficients associated with rotational Raman transitions of carbon monoxide (CO), obtained using time-resolved picosecond rotational coherent anti-Stokes Raman scattering spectroscopy. The dependencies of the CO self-broadening coefficients on rotational quantum number, J, and temperature are described for the J=3-16 lines of S-branch (ΔJ=+2) transitions for T=295-600 K at atmospheric pressure. Further, we report collisional linewidths of CO and collision partners N2 and CO2. The obtained S-branch linewidths of self-broadened CO agree well with previously reported frequency-domain experimental spectroscopy results, whereas the mixture-linewidth broadening coefficients differ from reported theoretical results by up to 80%.
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