Abstract
This work deals with the evaluation of the aqueous concentrations of dissolved reactive phosphorus (DRP), total phosphorus (TP), and ammonium nitrogen (N-NH4) in surface water by means of direct online instrumentation. A portable, submersible, and automated analyzer designed to measure dissolved and total nutrient concentrations characterized by miniaturization of the entire analytical process was tested against laboratory methods. A total number of 36 water samples of different origin (i.e., rain, river, lake, and sewage waters) were analyzed and used in the comparison of DRP, TP, and N-NH4 data. Raw data were distributed in a broad range of concentrations: 5-299μg P/L for DRP, 7-97μg P/L for TP, and 11-332μg N/L for N-NH4. Regression analysis underlined a high significant correlation between the measures of the probe and those of the laboratory (0.6<R 2<0.9; p<0.001) and pointed out the effectiveness of the new instrument in representing a broad range of nutrient concentrations.
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