Direct evidence of the non-uniform electrodeposition of zinc at the early stage

Abstract

Aqueous zinc-ion batteries (ZIBs) are regarded as one of the most promising electrical energy-storage systems for their eco-friendliness, low cost and high-safety. Although there have been a lot of studies recently on the Zn metal anode, little attention has been paid to its initial nucleation and growth behavior, which is critical to the understanding of fundamental mechanisms of the Zn plating. Herein, the digital holographic surface imaging (DHSI) method, combined synchronously with electrochemical tests, is employed to in-situ observe the non-uniform concentration changes on the surface of the copper substrate caused by the Zn nucleation and growth at the early stage. It is the first time to observe the early uneven depositions from a perspective of solution concentration changes in a symmetrical battery system. Results show that the later dendritic growth of Zn is closely related to the nucleation and earlier deposition process. Based on the phase maps obtained with in-situ DHSI technique, the nucleation and growth during the Zn electrodeposition can be closely investigated and vividly demonstrated, offering a promising avenue towards the understanding of the interfacial electrochemistry in all aqueous metal-ion batteries.