Abstract
AbstractThe electrochemical oxidation of anodic zinc in an acetonitrile solution of a Schiff base derived from Hpyrrole‐2‐carbaldehyde and N‐methylethylenediamine gives [Zn(C8H13N3)−(C9H11N3O2)], whose crystal structure has been determined. The compound crystallizes in the orthorhombic space group Pbca (No. 61) with a = 13.757(2), b = 17.748(4), c = 14.808(4) Å and Z = 8. Refinement converged to R = 0.049 for 1407 independent observed reflections. The crystal structure consists of monomeric molecules in which the central ZnN4O unit has distorted trigonal bipyramidal geometry and the carbamato group is monodentate.
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