Abstract

Abstract Recovery of organic fluorine by direct aluminum monofluoride molecular absorption spectrophotometry, following injection of samples into the graphite furnace and use of sodium fluoride standards, varies from 0 to 100% from compound to compound depending on the compound's volatility and the mechanism of thermal decomposition. This problem has now been overcome by employing standards made from the very same fluorochemical that is present in the sample. This approach is applicable to samples containing only 1 known fluorochemical. Some industrial applications of this technique that meet the needs of quality control, industrial hygiene policies, and certain U.S. Food and Drug Administration regulations are described.

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