Direct determination of cadmium in solids using a capacitively coupled microwave plasma atomic emission spectrometer

Abstract

A capacitively coupled microwave plasma (CMP) operating at 800 W was examined for the direct determination of cadmium in solids. The laboratory-constructed system contained a tungsten cup electrode capable of holding microsample quantities. A low-powered plasma was used to heat the sample, while at higher powers the plasma was used for sample vaporization and excitation. This plasma enabled thermal vaporization (TV) sample introduction to be accomplished in situ as the plasma formed directly around the sample. Thus, the need for sample preparation, procedural steps and sample transport was eliminated. This technique was capable of the direct determination of trace elements in solid samples in less than 5 min. The effects of experimental parameters such as gas flow rate, atomization power and electrode position were investigated. Detection limits obtained for Cd by TV-CMP-AES were in the picogram range with a relative standard deviation of <20%. The accuracy and precision of the method were also evaluated by measuring Cd in several NIST Standard Reference Materials.