Direct Contact Membrane Distillation for Treatment of Mixed Wastewater of Humic Acid and Reactive Dye: Membrane Flux Decline and Fouling Analysis.

Abstract

The main waste stream from the textile industry is its wastewater with high color, organic matters, and other contaminants. This study aims to investigate the effect of humic acid in mixed wastewater of humic acid and reactive dye on the treatment performance and permeate flux of a direct contact membrane distillation (DCMD) system. In this research, feed temperature and humic acid concentration were the main input parameters for the analysis of DCMD system operation. The fouling resistances significantly increased with higher humic acid concentrations in the mixed wastewater. As compared with the DI water test, 23% of flux decline occurred when the humic concentration in the wastewater was increased up to 20 mg/L. After the DCMD treatment, the 25 ADMI residual color was detected in the permeate when the mixed wastewater contained 20 mg/L humic acid. The mathematical model, based on the Antione equation, was proposed to predict the membrane flux decline of the DCMD system. The reduced pore size of the cake layer by a dimensionless constant β from the Kelvin equation was also considered for the fouling calculation to describe the transport mechanism.