Abstract
Neue Horizonte für Azide: Die Rhodium-katalysierte intermolekulare direkte C-H-Aminierung von Arenen mit Alkylaziden bietet eine bequeme Route zu N-Alkylanilinen (siehe Schema; DG=dirigierende Gruppe). Alkylazide mit verschiedensten funktionellen Gruppen reagierten bereitwillig mit diversen Substraten wie Benzamiden, aromatischen Ketonen und Flavonen.
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