Abstract

Indium nitride has a good potential for infrared optoelectronics, yet it suffers from fast nonradiative recombination, the true origin of which has not been established with certainty. The diffusion length of free carriers at high densities is not well investigated either. Here, we study carrier recombination and diffusion using the light-induced transient grating technique in InN epilayers grown by pulsed MOCVD on c-plane sapphire. We show that direct Auger recombination governs the lifetime of carriers at densities above ~1018 cm−3. The measured Auger recombination coefficient is (8 ± 1) × 10−29 cm−3. At carrier densities above ~5 × 1019 cm−3, we observe the saturation of Auger recombination rate due to phase space filling. The diffusion coefficient of holes scales linearly with carrier density, increasing from 1 cm2/s in low-doped layers at low excitations and up to ~40 cm2/s at highest carrier densities. The resulting carrier diffusion length remains within 100–300 nm range, which is comparable to the light absorption depth. This feature is required for efficient carrier extraction in bipolar devices, thus suggesting MOCVD-grown InN as the material fit for photovoltaic and photonic applications.

Highlights

  • Indium nitride with a direct band gap of 0.7 eV1 is an attractive material for infrared optoelectronics

  • Linear or sublinear dependences were observed in InN layers by using the time-resolved photoluminescence, differential reflectance, or light-induced transient gratings (LITG) techniques

  • The samples are grown by using metalorganic chemical vapor deposition (MOCVD) technique, which is most prospective for growing InN epilayers for photovoltaics and other applications on industrial scale

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Summary

Methods

A set of InN layers comprising 20 samples was grown using a close-coupled showerhead 3 × 2′′ MOCVD reactor (Aixtron). The photoexcited carrier density can be accurately estimated as Δn = αI/hν, where α is the absorption coefficient, I is the excitation energy fluence (“excitation intensity”), and hν is the photon quantum energy; note that Δn represents an averaged photoexcited carrier density over the period of transient grating at the very surface of a sample. This part of transient decay was used to study the dependences τ(n0 + Δn) and D(n0 + Δn). This regime was used to study the dependence τ(n0)

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