Abstract
Electron donor–acceptor (EDA) complexes are interesting chemical species that function as molecular complexes. In this context, chemists have actively studies the use of halogen bonding as a noncovalent interaction in photochemistry. This study focused on developing a direct arylation reaction using aryl radicals generated by photoinduced electron transfer (PET) through halogen-bonding interactions. The study also involves optimizing reaction conditions for a photo induced direct arylation reaction using phenols as halogen bonding acceptor and plausible reaction mechanism. Our results demonstrated that this method provides a facile and efficient approach for synthesizing complex biaryls containing heteroarens using readily available heteroarenes.
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