Abstract
Treatment of a triruthenium complex having μ3-methylidyne and μ3-propyne ligands, (Cp*Ru)3(μ3-CH)(μ3-η2-HCCMe)(μ-H)2 (6), with benzene results in arylation of the propyne ligand via the C−H bond activation of benzene to yield the μ3-phenylmethylacetylene complex (Cp*Ru)3(μ3-CH)(μ3-η2:η2(⊥)-PhCCMe) (7). An X-ray diffraction study of 7 clearly established that regiospecific arylation occurred at the terminal position of the propyne ligand.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
