Abstract
The title compound is an AB-type salt with a completely ordered anion sublattice. Because of the strong trans influence of the Br ligands, both Os—Br bonds, of 2.466 (1) and 2.468 (1) Å, are shortened compared to those reported for K2[OsBr6] (2.51 Å). However, only one of the two F ligands coordinated trans to a Br ligand exhibits a longer Os—F distance [1.968 (4) Å] than those along the symmetrically coordinated F—Os—F axis [1.930 (4) and 1.929 (4) Å].
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