Abstract
ABSTRACTExperimental and theoretical photoabsorption cross sections combined with constraints provided by the Kuhn–Reiche–Thomas sum rule, the high-energy behaviour of the dipole oscillator strength density, static dipole polarisabilities, and molar refractivity data when available are used to construct dipole oscillator strength distributions for PH3, PF3, PF5, PCl3, SiCl4, GeCl4, and SnCl4. The distributions are used to predict dipole sum rules S(k), mean excitation energies I(k), and van der Waals C6 coefficients.
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