Abstract
1. In systems with a nonsymmetrical arrangement of the unshared electron pairs (UEP) relative to the axis of symmetry, the dipole moments (DM) of the UEP must be taken into consideration, while in systems with a symmetrical arrangement of the UEP, the DM of the UEP enter into the DM of the bonds obtained according to an additive scheme. 2. A quantum mechanical consideration of the DM of the C-O, C-S, and S-O bonds, as well as the UEM of the sulfur atom, was performed by the MO LCAO method. 3. The most probable values of the DM of the bonds and UEP were calculated for an additive calculation of the DM of molecules of sulfides, sulfites, and sulfoxides.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
