Abstract
The dielectric constants and refractions of solutions of benzene, p-xylene and mesitylene containing silver perchlorate have been measured. For very low concentrations in benzene, a dipole moment of 10.7 D was confirmed but in more concentrated solutions a value of 4.7 D was obtained. For p-xylene and mesitylene only one value was obtained: 2.7 D in the case of p-xylene solutions and 4.3 D for mesitylene solutions. This behaviour is discussed in terms of ion pair association and donor-acceptor interactions taking place in such systems between the aromatic species and the silver ion.
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