Abstract
Dipole moments have been determined by static polarization measurements for the copper(II) chelates of the fluorinated β-diketones RCOCH 2COCF 3 (R = 2-thienyl, Ph, p-MeC 6H 4, p-ClC 6H 4, m-ClC 6H 4, p-BrC 6H 4, and m-BrC 6H 4). The moments, which range from 2.47 to 4.82D, indicate a cis-square-planar structure for the copper chelates. The variation of the dipole moments with R is considered to be dependent on (a) the Ph-X bond moment, (b) the inductive effect of the meta- and para-substituent X, and (c) the mesomeric effect of X (X = Cl, Br, Me).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
