Abstract

1. The aryl acetate conformations show a planar ester group, and cis-oriented C=0 and C-0 bonds, the aryl radical being rotated out of the bond plane by 65°. 2. In the trifluoroacetates, the aryl radical rotation has diminished to 25°. 3. The dipole moments of the ester oxygen atom bonds are not additive in the acetates and their analogs.

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