Abstract

Dipole moments of the charge-transfer complexes of some sulfur (sulfide and thiocarbonyl) and oxygen (ether and carbonyl) donors with iodine have been determined and the various charge-transfer parameters have been calculated by making use of the charge-transfer transition energies and heats of formation of the complexes. The contribution of the charge-transfer structure in the ground state appears to be greater in the complexes of sulfur donors than in the complexes of oxygen donors.

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