Abstract
The microwave spectrum of the heterodimer HCN…HF is reported, the collinearity of the nuclei established, and r 0(N…F)=2.796 Å obtained. From the Stark effect, μ 0(HCN…HF)=5.59 ± 0.02 D which indicates an enhancement of 0.78 D over the vector sum of the monomer values.
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