Abstract
Ruthenium(II) dichloride complexes with (+)- and (–)-2,2′-bis(diphenylphosphino)-4,4′,6,6′-tetramethyl-3,3′-bibenzo[b]thiophene (1a), new chiral atropisomeric heterocyclic ligands, reduce α- and β-oxoesters to α- and β-hydroxyesters with an enantiomeric purity comparable, if not higher, to that reported for binap under the same experimental conditions.
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