Abstract
AbstractA dioxygen‐triggered selectively difunctionalization of olefins to achieve β‐hydroxysulfones has been developed. Particularly, the mechanism of this reaction can be controlled by DABCO, which act as a single electron transfer reagent, to selectively obtain ketosulfone or hydroxysulfone. The reaction was conducted in a clean, safe, mild, and catalyst‐free conditions. Moreover, as a proof‐of‐concept, two bioactive molecules were synthesized easily using this method.
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