Abstract
Diorganomorpholinometalates of Gallium and Indium – Monomer-Dimer-Equilibrium in Solution The reaction of Li[N(CH2CH2)2O] (LiMorpholinate; Li(Morph)) with Me2GaCl and Me2InCl gives by salt-elimination the diorganoamidometalates Me2M(Morph) ( M = Ga: 1; M = In: 2), respectively. 1 and 2 were characterized by NMR and vibrational spectroscopy as well as by X-ray structure determinations. According to this, centrosymmetrical dimers are present in the solid state while a monomer-dimer equilibrium was assumed for the THF-solution. Cryoscopic molecular weight determinations confirmed our assumptions.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
