Abstract
The reaction of NH{sub 2}(X {sup 2}B{sub 1}) with NO{sub 2} was studied at room temperature using time-resolved infrared diode laser spectroscopy to detect N{sub 2}O, H{sub 2}O, and NO products. The N{sub 2}O + H{sub 2}O product channel was found to have a branching ratio of 0.14{+-}0.02. Large amounts of NO were detected, but secondary sources of this species prevent a quantitative determination of the branching ratio into the H{sub 2}NO + NO channel. These results are in contrast to previously published branching ratio data. 42 refs., 4 figs., 1 tab.
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