Abstract
Abstract The Stark effect was used to assign four series of the transitions in the heavily perturbed spectrum of methanethiol in the 14 μm region: K=0 and two K=1 series of A torsional symmetry and K=0 series of E symmetry. Effective parameters were determined for each series. The K=0 levels of A symmetry in the ν8 state were found to be perturbed by a Fermi-type resonance.
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