Diode laser measurements of temperature-dependent line parameters for water vapor near 820 nm

Abstract

Air- and self-broadening coefficients and relative line strenghts for 8–10 low-J lines in the (2 1 1) vibrational band of water vapor have been accurately measured over the T = 330–540 K range using an 817–824 nm GaAlAs diode laser. The technique of wavelength modulation with third-harmonic line locking and second-harmonic detection was used to derive the line parameters with accuracies of several percent from measurements with absorptivities as low as 2 x 10 -3. The linewidths and temperature coefficients are in good agreement with theoretical calculations and with recent measurements in the (2 2 1) and (3 0 1) bands. Absolute line strenghts have been derived from measurements on two of the lines and are found to be 21 ±4% higher than the values listed in the 1991 HITRAN compilation.