Abstract
An interesting metallo-organic polymeric architecture of a Zn(II) dinuclear pendant-armed macrocyclic complex was obtained. The structure consists of a supramolecular architecture of infinite pillars comprised of [Zn2L(NO3)2]2+ units and free nitrate ions. This structure has tubular channels along the c-axis, and these are stabilized by the presence of multiple inter- and intramolecular π,π-stacking interactions. A flow of uncoordinated nitrate anions is present within the channels.
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