Abstract
Three silver(I) coordination complexes of diaza- and dibenzo-crown ethers, [Ag(DDAC)](CF 3SO 3) ( 1) [Ag 2(DDAC)(CF 3SO 3) 2] ( 2) and [Ag 2(DB24C8)(CF 3SO 3) 2] ( 3) have been synthesized by using different molar ratios of ligand to silver triflate salt, and characterized structurally. A large excess of DDAC ligand leads to mononuclear complex 1, and a large excess of silver triflate gives rise to dinuclear complex 2, based on metal–heteroatom and metal–oxygen interactions. Ligand DB24C8 coordinates two silver(I) ions to afford dinuclear complex 3.
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