Abstract
A novel rhodium species grafted onto a polymer has been prepared by reacting the functionalized resin (Res-PPh 2) with [Rh 2(μ-S tBu) 2(CO) 4] to afford [Rh 2(μ-S tBu) 2(CO) 2 (Res-PPh 2) 2]. This complex catalyses the hydrofomylation of oct-1-ene under mild conditions with 99–100% selectivity in aldehydes and more than 90% selectivity in linear aldehyde. A peculiar inhibiting effect of dihydrogen has been shown.
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