Abstract
Zn(II), Cu(II), Ni(II), Co(II), Fe(II) and Mn(II) dinuclear complexes of the bisbidente N 4-donor, N, N′-bis(2-tosylamino-benzylidene)-4,4′-oxodianiline (H 2ODTs), have been prepared and characterised. FAB mass spectroscopy evidences through the isotopic profiles of [M 2(ODTs) 2] + species, the dimeric nature of these metal compounds. Magnetic studies for Co 2(ODTs) 2 · 4H 2O show that the thermal evolution of 1/ χ M obeys Curie–Weiss law and that both the values of χ M T and the shape of the curve, are typical for almost isolated Co II ions.
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