Abstract

Organometallic palladium(II) complexes obtained by cyclometallation reactions of azobenzene ligands or Schiff bases are of considerable interest in the context of practical applications such as lumunescent or liquid-crystalline materials. The shape and the dimensions of the molecules can play an important role in the physical properties of these new molecular materials. Various dinuclear cyclopalladated azobenzene complexes structurally characterised are reviewed with the intention to provide insights into the design of new dimeric metallomesogens with a suitable molecular shape.

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