Abstract
The preparation and characterization of an original N,N′-disubstituted oxamide derivative are reported. This compound is distinguished by the occurrence of substituents with terminal NH 2 groups which can be used in further reactions. Thus by reaction with salicylaldehyde one obtains a new dinucleating ligand which affords the first examples of vanadium(IV) and iron(III) oxamido-bridged dinuclear complexes. The spectroscopic characteristics and magnetic properties of these complexes and the related nickel(II) and copper(II) complexes are reported.
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