Abstract
The title compound, [Fe(NO)2(C21H21P)2], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)2(L)x, referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)2 L 2], with L = P(C6H4-p-CH3)3. There are two crystallographically independent but chemically equal molecules per asymmetric unit. The iron atom in each molecule is tetrahedrally coordinated by two phosphane ligands and two NO groups, with Fe—N—O angles in the range 173.84 (15)–179.31 (16)°.
Highlights
The title compound, [Fe(NO)2(C21H21P)2], belongs to the family of metal dinitrosyl compounds with the general formula
The iron atom in each molecule is tetrahedrally coordinated by two phosphane ligands and two NO groups, with Fe—N—O angles in the range 173.84 (15)–179.31 (16)
The starting compound, Fe(NO)2(CO)2, was prepared using a published method described by Eisch & King (1965)
Summary
The title compound, [Fe(NO)2(C21H21P)2], belongs to the family of metal dinitrosyl compounds with the general formula. 0.34 0.29 0.29 mm Bruker APEX CCD diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 2001) We report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)2L2], with L = The iron atom in each molecule is tetrahedrally coordinated by two phosphane ligands and two NO groups, with Fe—N—O angles in the range 173.84 (15)–179.31 (16) .
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.