Abstract

Glatte Trennung: Mit Distickstoff reagieren Lösungen des Hydridkomplexes [K(dme)]2[{Nb}2(μ-H)4] (siehe Schema) unter Bildung des Nitridkomplexes [K(thf)2]2[{Nb}2(μ-N)2] und H2. Bei diesem Prozess wird die Dreifachbindung von Distickstoff gespalten. Die Nitridliganden sind mit MeI stufenweise alkylierbar, wobei über einen Nitrid-Imid-Komplex schließlich ein Bis(imid)komplex entsteht. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z703336_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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