Abstract
AbstractBorylation of hafno‐ and zirconocene complexes [(η5‐C5H2‐1,2,4‐Me3)2M]2(μ2,η2,η2‐N2), containing strongly activated dinitrogen ligands, with pinacolborane (HBPin) resulted in N–B and M–H bond formation. Treatment of the borylated products with carbon monoxide triggered N–N bond scission with concomitant N–C bond formation to produce μ‐borylimido and μ‐formamidido fragments. Conversely, addition of tBuNC resulted in insertion of the isocyanide ligand into the M–H bonds and furnished the corresponding η2‐iminoacylhafnocene complexes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
