Abstract

Distickstoff aktiviert und gespalten: Bei der Reaktion des verbrückten Aryloxid-Niob-Komplexes 1 mit einem Hydrierungsmittel entsteht das Nitrid-verbrückte Dimer 2. Wie aus einem analogen Experiment unter 15N2-Atmosphäre hervorgeht, stammt der Nitridligand aus N2.

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