Year-end Sale % OFF 
Abstract
We report the first tris(alkoxide)V(III) complex to bind dinitrogen. Removal of THF from V(OR)(3)THF furnishes the highly reactive V(OR)(3) fragment, which binds dinitrogen to form [V(OR)(3)](2)(μ-N(2)) in the solid state. Dinitrogen is readily released upon dissolution of the complex. Structural and DFT studies are consistent with significant activation of N(2) when bound by the vanadium tris(alkoxide) platform.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
