Abstract
In the title compound, (C6H10N2)[FeBr4], the asymmetric unit contains one half-cation and one half-anion, where the Fe atom has a distorted tetrahedral environment. The Fe atom and two Br atoms lie on a mirror plane; the cation is centrosymmetric. In the crystal structure, the cations and anions are packed into alternate stacking with no significant intermolecular Br⋯Br and/or aryl⋯aryl interactions within each stack. The anion⋯anion stacks interact via Br⋯Br interactions [Br⋯Br = 3.8773 (15) Å] to form one-dimensional arrays. The Br⋯aryl interactions are arranged in a ⋯Br⋯aryl⋯Br⋯aryl⋯ infinite motif [Br⋯centroid distance of 3.928 (1) Å]. All of them link the anions and cations into two-dimensional layers.
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More From: Acta Crystallographica Section E Structure Reports Online
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