Abstract
The crystal structure of the title compound, [Mn(TDC)]4[Re6Se8(CN)6]·13H2O, contains discrete [Re6Se8(CN)6]4− and Mn(TDC)+ moieties [TDC is the tetrakis(2,6-dichlorophenyl)porphinate dianion, C44H20Cl8N42−]. The anion as well as two of the cations lie on crystallographic centers of symmetry. Each Mn(TDC)+ cation is octahedral with two axial methanol ligands. The coordinated methanol groups form O—H⋯O hydrogen bonds to solvent water molecules of crystallization in the lattice.
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