Abstract
The molecule of the title compound, [Na(C13H11N3O)2(CH3OH)2]I, is non-planar, with the Na atom chelated by the O atoms and the N atoms of two N′-(3-pyridylmethylene)benzohydrazide ligands and both O atoms of two methanol ligands. The asymmetric unit consists of one half-molecule. The Na atom is located on a crystallographic centre of inversion. The six-coordinate Na atom adopts a distorted octahedral coordination. In the crystal structure, intermolecular N—H⋯I and O—H⋯N hydrogen bonds link the molecules into a two-dimensional network.
Highlights
The molecule of the title compound, [Na(C13H11N3O)2(CH3OH)2]I, is non-planar, with the Na atom chelated by the O atoms and the N atoms of two N0 -(3-pyridylmethylene)benzohydrazide ligands and both O atoms of two methanol ligands
The asymmetric unit consists of one halfmolecule
The Na atom is located on a crystallographic centre of inversion
Summary
R factor = 0.037; wR factor = 0.104; data-to-parameter ratio = 14.0. The molecule of the title compound, [Na(C13H11N3O)2(CH3OH)2]I, is non-planar, with the Na atom chelated by the O atoms and the N atoms of two N0 -(3-pyridylmethylene)benzohydrazide ligands and both O atoms of two methanol ligands. The asymmetric unit consists of one halfmolecule. The Na atom is located on a crystallographic centre of inversion. The six-coordinate Na atom adopts a distorted octahedral coordination. Intermolecular N—H I and O—H N hydrogen bonds link the molecules into a two-dimensional network
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