Abstract

Tryptophan-linked dimeric diketopiperazine alkaloids possess great molecular diversity and bioactivity. In this issue of <i>Chem</i>, Jiang and co-workers report an oxidative approach to those alkaloids containing an unsymmetrical C3-N1′ linkage. In their concise synthesis of (+)-asperazine, they successfully dimerized a designer tryptophan-alternative building block through the sustained release of electrophilic iodine.

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