Dimensional analysis applied to pitting corrosion measurements

Abstract

In this work, two new indices, S E and S G are proposed to evaluate pitting corrosion by dimensional analysis of three parameters of PSD, the slope of high frequency linear region ( k), the critical frequency ( f c) and the low-frequency plateau level ( W). And then they are employed to analyze the potential electrochemical noise obtained during the corrosion processes of stainless steel 1Cr18Ni9Ti and pure Al, two materials most susceptible to pitting corrosion in NaCl solutions. Meanwhile another two mathematical methods, statistics and wavelet transform techniques, are also carried on the same potential oscillation data to estimate the function (meaning) of these two indices ( S E and S G) in monitoring corrosion processes. The results suggest that, the index S E is directly proportional to the rapider potential oscillating and higher fluctuation amplitude and can be used to depict the distribution behavior of electrochemical noise, while the index S G can be used to depict the slower corrosion processes.