Abstract
Metastable solid solutions (SS) Mn3FeTiSbO9 and Mn4FeTi2SbO12 with the ilmenite structure (space group R\(\bar 3\)) have been prepared by quenching at normal conditions. The compositions of the compounds have been justified using EDX spectroscopy and X-ray diffraction. The magnetic properties of SSs have been analyzed by comparison with ferrimagnetic ilmenite Mn2FeSbO6 (TN = 269 K) as a natural mineral and ceramics obtained at high pressure and high temperature. The solid solutions have been characterized as dilute magnetic systems formed as a result of substitution of nonmagnetic cations Ti4+ for a part of Fe3+ and Sb5+ cations. Mn3FeTiSbO9 is considered as a ferromagnetic with TN = 171 K and Mn4FeTi2SbO12 as a magnetic with the concentration of magnetic clusters below the percolation threshold.
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