Abstract

We present a dilatation transformation analysis on curvilinear reaction path, and analyze the curvature effect of complex scaling on the prediction of molecular reaction threshold resonance. An example of numerical calculation was carried out for the prediction of threshold resonance of H + H2 molecular scattering with and without consideration of the reaction path curvature. We found, in the studied system, that the curvature provides a correction to threshold resonance lifetime as large as 25%.

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