Abstract
The crystal structure of hexacarbonyl-μ-(chloromethylsilyl)-bis[μ-(dimethylsilyl)]diiron(Fe-Fe), [Fe 2 (CH 3 ClSi)(C 2 H 6 Si) 2 (CO) 6 ], has been determined. The Fe-Fe distance is 2.705(1)A and the Fe-Si distances are 2.322 (3) A. The combination of the sixfold screw axis and the uniqueness of the bridging SiMeCl moiety create rotational disorder within the unit cell.
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More From: Acta Crystallographica Section C Crystal Structure Communications
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