Abstract
The asymmetric unit of the title compound, [ZnI2(C12H10N2O2)2], obtained from the reaction of 4-(4-nitrobenzyl)pyridine with zinc(II) iodide, contains two independent discrete distorted tetrahedral complex units [Zn—I = 2.5472 (8)–2.5666 (7) Å and Zn—N = 2.044 (4)–2.052 (4) Å], which are essentially identical conformationally. The crystal used for measurement was a racemic twin.
Highlights
[ZnI2(C12H10N2O2)2], obtained from the reaction of 4-(4nitrobenzyl)pyridine with zinc(II) iodide, contains two independent discrete distorted tetrahedral complex units [Zn—I =
All su's are estimated from the variances of the variance-covariance matrix
The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2
Summary
Graham Smith,a* Urs D. Wermutha and Michael L. Williamsb a Faculty of Science and Technology, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia, and bSchool of Biomolecular and Physical Sciences, Griffith University, Nathan, Queensland 4111, Australia R factor = 0.032; wR factor = 0.056; data-to-parameter ratio = 16.1. [ZnI2(C12H10N2O2)2], obtained from the reaction of 4-(4nitrobenzyl)pyridine with zinc(II) iodide, contains two independent discrete distorted tetrahedral complex units [Zn—I = 2.5472 (8)–2.5666 (7) Å and Zn—N = 2.044 (4)–2.052 (4) Å], which are essentially identical conformationally. The crystal used for measurement was a racemic twin.
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More From: Acta Crystallographica Section E Structure Reports Online
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